What follows are the names and formulas for the first eight normal, or unbranched, alkanes. Note that the first four of these received common names before their structures were known; from C 5 onward, however, they were given names with Greek roots indicating the number of carbon atoms (e.g., octane, a reference to “eight.”)
The reader will undoubtedly notice a number of familiar names on this list. The first four, being the lowest in molecular mass, are gases at room temperature, while the heavier ones are oily liquids. Alkanes even heavier than those on this list tend to be waxy solids, an example being paraffin wax, for making candles. It should be noted that from butane on up, the alkanes have numerous structural isomers, depending on whether they are straight or branched, and these isomers have differing chemical properties.
Branched alkanes are named by indicating the branch attached to the principal chain. Branches, known as substituents, are named by taking the name of an alkane and replacing the suffix with yl—for example, methyl, ethyl, and so on. The general term for an alkane which functions as a substituent is alkyl.