Though atoms differ, subatomic particles do not. There is no such thing, for instance, as a “hydrogen proton”—otherwise, these subatomic particles, and not atoms, would constitute the basic units of an element. Given the unvarying mass of subatomic particles, combined with the fact that the neutron only weighs 0.16% more than a proton, the established value of 1 amu provides a convenient means of comparing mass. This is particularly useful in light of the large numbers of isotopes—and hence of varying figures for mass—that many elements have.
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ATOMIC MASS UNITS AND THE PERIODIC TABLE.
The periodic table as it is used today includes figures in atomic mass units for the average mass of each atom. The value is actually 1.008 amu, reflecting the presence of slightly heavier deuterium isotopes in the average sample of hydrogen
Figures increase from hydrogen along the periodic table, though not by a regular pattern. Sometimes the increase from one element to the next is by just over 1 amu, and in other cases, the increase is by more than 3 amu. This only serves to prove that atomic number, rather than atomic mass, is a more straightforward means of ordering the elements.
Mass figures for many elements that tend to appear in the form of radioactive isotopes are usually shown in parentheses. This is particularly true for elements with very, very high atomic numbers (above 92), because samples of these elements do not stay around long enough to be measured.
ELEMENTS
As of 2001, there were 112 known elements, of which about 90 occur naturally on Earth. Uranium, with an atomic number of 92, was the last naturally occurring element discovered: hence some sources list 92 natural elements. Other sources, however, subtract those elements with a lower atomic number than uranium that were first created in laboratories rather than discovered in nature. In any case, all elements with atomic numbers higher than 92 are synthetic, meaning that they were created in laboratories. Of these 20 elements—all of which have appeared only in the form of radioactive isotopes with short half-lives—the last three have yet to receive permanent names.
In addition, three other elements—designated by atomic numbers 114, 116, and 118, respectively—are still on the drawing board, as it were, and do not yet even have temporary names. The number of elements thus continues to grow, but these “new” elements have little to do with the daily lives of ordinary people. Indeed, this is true even for some of the naturally occurring elements: for example, few people who are not chemically trained would be able to identify yttrium, which has an atomic number of 39.
Though an element can exist theoretically as a gas, liquid, or a solid, in fact, the vast majority of elements are solids. Only 11 elements exist in the gaseous state at a normal temperature of about 77°F (25°C). These are the six noble gases; fluorine and chlorine from the halogen family; as well as hydrogen, nitrogen, and oxygen. Just two are liquids at normal temperature: mercury, a metal, and the nonmetal halogen bromine.
CHEMICAL NAMES AND SYMBOLS
For the sake of space and convenience, elements are listed on the periodic table by chemical symbol or element symbol—a one-or two-letter abbreviation for the name of the element according to the system first developed by Berzelius. These symbols, which are standardized and unvarying for any particular element, greatly aid the chemist in writing out chemical formulas, which could otherwise be quite cumbersome.
Many of the chemical symbols are simple one-letter designations: H for hydrogen, O for oxygen, and F for fluorine. Others are two-letter abbreviations, such as He for helium, Ne for neon, and Si for silicon. In many cases, the two-letter symbols indicate the first and second letters of the element’s name, but this is not nearly always the case. Cadmium, for example, is abbreviated Cd, while platinum is Pt.
Many of the one-letter symbols indicate elements discovered early in history. For instance, carbon is represented by C, and later “C” elements took two-letter designations: Ce for cerium, Cr for chromium, and so on. Likewise, krypton had to take the symbol Kr because potassium had already been assigned K. The association of potassium with K brings up one of the aspects of chemical symbols most confusing to students just beginning to learn about the periodic table: why K and not P? CHEMICAL SYMBOLS BASED IN OTHER LANGUAGES.
In fact, potassium’s symbol is one of the more unusual examples of a chemical symbol, taken from an ancient or non-European language. Soon after its discovery in the early nineteenth century, the element was named kalium, apparently after the Arabic qali or “alkali.” The use of Arabic in naming potassium is unusual in the sense that “strange” chemical symbols usually refer to Latin and Greek names. Latin names include aurum, or “shining dawn” for gold, symbolized as Au; or ferrum, the Latin word for iron, designated Fe. Likewise, lead (Pb) and sodium (Na) are represented by letters from their Latin names, plumbum and natrium, respectively.
Some chemical elements are named for Greek or German words describing properties of the element. Consider, for instance, the halogens, collectively named for a Greek term meaning “salt producing.” Chloros, in Greek, describes a sickly yellow color, and was assigned to chlorine; the name of bromine comes from a Greek word meaning “stink”; and that of iodine is a form of a Greek term meaning “violet-colored.” Astatine, last-discovered of the halogens and the rarest of all natural elements, is so radioactive that it was given a name meaning “unstable.”
NAMES OF LATER ELEMENTS.
The names of several elements with high atomic numbers—specifically, the lanthanides, the transuranium elements of the actinide series, and some of the later transition metals—have a number of interesting characteristics. Several reflect the places where they were originally discovered or created: for example, germanium, americium, and californium. Other elements are named for famous or not-so-famous scientists. Most people could recognize einsteinium as being named after Albert Einstein (1879-1955), but the origin of the name gadolinium—Finnish chemist Johan Gadolin (1760-1852)—is harder for the average person to identify. Then of course there is element 101, named mendelevium in honor of the man who created the periodic table.
Two elements are named after women: curium after French physicist and chemist Marie Curie (1867-1934), and meitnerium after Austrian physicist Lise Meitner (1878-1968). Curie, the first scientist to receive two Nobel Prizes—in both physics and chemistry—herself discovered two elements, radium and polonium. In keeping with the trend of naming transuranium elements after places, she commemorated the land of her birth, Poland, in the name of polonium. One of Curie’s students, French physicist Marguerite Perey (1909-1975), also discovered an element and named it after her own homeland: francium.
Meitnerium, the last element to receive a name, was created in 1982 at the Gesellschaft für Schwerionenforschung, or GSI, in Darmstadt, Germany, one of the world’s three leading centers of research involving transuranium elements. The other two are the Joint Institute for Nuclear Research in Dubna, Russia, and the University of California at Berkeley, for which berkelium is named.
THE IUPAC AND THE NAMING OF ELEMENTS.
One of the researchers involved with creating berkelium was American nuclear chemist Glenn T. Seaborg (1912-1999), who discovered plutonium and several other transuranium elements. In light of his many contributions, the scientists who created element 106 at Dubna in 1974 proposed that it be named seaborgium, and duly submitted the name to the International Union of Pure and Applied Chemistry (IUPAC).
Founded in 1919, the IUPAC is, as its name suggests, an international body, and it oversees a number of matters relating to the periodic table: the naming of elements, the assignment of chemical symbols to new elements, and the certification of a particular research team as the discoverers of that element. For many years, the IUPAC refused to recognize the name seaborgium, maintaining that an element could not be named after a living person. The dispute over the element’s name was not resolved until the 1990s, but finally the IUPAC approved the name, and today seaborgium is included on the international body’s official list.
Elements 110 through 112 had yet to be named in 2001, and hence were still designated by the three-letter symbols Uun, Uuu, and Uub respectively. These are not names, but alphabetic representations of numbers: un for 1, nil for 0, and bium for 2. Thus, the names are rendered as ununnilium, unununium, and ununbium; the undiscovered elements 114, 116, and 118 are respectively known as ununquadium, ununhexium, and ununoctium.
TWO SYSTEMS FOR LABELING GROUPS.
Having discussed the three items of information contained in the boxes of the periodic table—atomic number, chemical symbol/name, and average atomic mass—it is now possible to step back from the chart and look at its overall layout. To reiterate what was stated in the introduction to the periodic table above, the table is arranged in rows called periods, and columns known as groups. The deeper meaning of the periods and groups, however—that is, the way that chemists now understand them in light of what they know about electron configurations—will require some explanation.
All current versions of the periodic table show seven rows—in other words, seven periods—as well as 18 columns. However, the means by which columns are assigned group numbers varies somewhat. According to the system used in North America, only eight groups are numbered. These are the two “tall” columns on the left side of the “dip” in the chart, as well as the six “tall” columns to the right of it. The “dip,” which spans 10 columns in periods 4 through 7, is the region in which the transition metals are listed. The North American system assigns no group numbers to these, or to the two rows set aside at the bottom, representing the lanthanide and actinide series of transition metals.
As for the columns that the North American system does number, this numbering may appear in one of four forms: either by Roman numerals; Roman numerals with the letter A (for example, IIIA); Hindu-Arabic numbers (for example, 3); or Hindu-Arabic numerals with the letter A. Throughout this book, the North American system of assigning Hindu-Arabic numerals without the letter A has been used. (Some scientists in North America are also adopting the IUPAC system.)
The IUPAC numbers all columns on the chart, so that instead of eight groups, there are 18. The table below provides a means of comparing the North American and IUPAC systems. Columns are designated in terms of the element family or families, followed in parentheses by the atomic numbers of the elements that appear at the top and bottom of that column. The first number following the colon is the number in the North American system (as described above, a Hindu-Arabic numerical without an “A”), and the second is the number in the IUPAC system.
Element Family North American IUPAC Hydrogen and alkaali metals (1, 87) 1 1 Alkaline metals (4, 88) 2 2 Transition metals (21,89) 3 Transition metals (22,104) 4 Transition metals (23,105) 5 Transition metals (24,106) 6 Transition metals (25,107) 7 Transition metals (26,108) 8 Transition metals (27,109) 9 Transition metals (28,110) 10 Transition metals (29,111) 11 Transition metals (30,112) 12 Nonmetals and metals (5,81) a 3 13 Nonmetals, metalloids, and metal (6,82) 4 14 Nonmetals, metalloids, and metal (7,83) 5 15 Nonmetals, metalloids, (8,84) 6 16 Halogens (9,85) 7 17 Noble gases (2,86) 8 18 Lanthanides (58,71) No number group assigned in either system Actinides (90,103) No number group assigned in either system
VALENCE ELECTRONS , PERIODS , AND GROUPS
The merits of the IUPAC system are easy enough to see: just as there are 18 columns, the IUPAC lists 18 groups. Yet the North American system is more useful than it might seem: the group number in the North American system indicates the number of valence electrons, the electrons that are involved in chemical bonding. Valence electrons also occupy the highest energy level in the atom—which might be thought of as the orbit farthest from the nucleus, though in fact the reality is more complex.
A more detailed, though certainly far from comprehensive, discussion of electrons and energy levels, as well as the history behind these discoveries, appears in the Electrons essay. In what follows, the basics of electron configuration will be presented with the specific aim of making it clear exactly why elements appear in particular columns of the periodic table.
PRINCIPAL ENERGY LEVELS AND PERIODS.
At one time, scientists thought that electrons moved around a nucleus in regular orbits, like planets around the Sun. The pattern of orbitals is determined by the principal energy level of the atom, which indicates a distance that an electron may move away from the nucleus.
Principal energy level is designated by a whole-number integer, beginning with 1 and moving upward: the higher the number, the further the electron is from the nucleus, and hence the greater the energy in the atom. Each principal energy level is divided into sublevels corresponding to the number n of the principal energy level: thus, principal energy level 1 has one sub-level, principal energy level 2 has two, and so on.
The relationship between principal energy level and period is relatively easy to demonstrate: the number n of a period on the periodic table is the same as the number of the highest principal energy level for the atoms on that row—that is, the principal energy level occupied by its valence electrons. Thus, elements on period 4 have a highest principal energy level of 4, whereas the valence electrons of elements on period 7 are at principal energy level 7. Note the conclusion that this allows us to draw: the further down the periodic table an element is positioned, the greater the energy in a single atom of that element. Not surprisingly, most of the elements used in nuclear power come from period 7, which includes the actinides.
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